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Technical Paper

Detection of Catalyst Failure On-Vehicle Using the Dual Oxygen Sensor Method

1991-02-01
910561
On-vehicle proof-of-concept testing was conducted to evaluate the ability of the dual oxygen sensor catalyst evaluation method to identify serious losses in catalyst efficiency under actual vehicle operating conditions. The dual oxygen sensor method, which utilizes a comparison between an upstream oxygen sensor and an oxygen sensor placed downstream of the catalyst, was initially studied by the Environmental Protection Agency (EPA) under steady-state operating conditions on an engine dynamometer and reported in Clemmens, et al. (1).* At the time that study was released, questions were raised as to whether the technological concepts developed on a test fixture could be transferred to a vehicle operating under normal transient conditions.
Technical Paper

Resistive Materials Applied to Quick Light-off Catalysts

1989-02-01
890799
The application of resistive materials as part of an exhaust emission control system is presented and discussed. The importance of cold start emissions is emphasized, and results are presented from experiments conducted with two different conductive materials. Most of the testing was conducted using methanol as the fuel, although some tests were run using gasoline-fueled vehicles.
Technical Paper

Catalysts for Methanol Vehicles

1987-11-01
872052
A Methanol catalyst test program has been conducted in two phases. The purpose of Phase I was to determine whether a base metal or lightly-loaded noble metal catalyst could reduce Methanol engine exhaust emissions with an efficiency comparable to conventional gasoline engine catalytic converters. The goal of Phase II was the reduction of aldehyde and unburned fuel emissions to very low levels by the use of noble metal catalysts with catalyst loadings higher than those in Phase I. Catalysts tested in Phase I were evaluated as three-way converters as well as under simulated oxidation catalyst conditions. Phase II catalysts were tested as three-way converters only. For Phase I, the most consistently efficient catalysts over the range of pollutants measured were platinum/rhodium configurations. None of the catalysts tested in Phase I were able to meet a NOx level of 1 gram per mile when operated in the oxidation mode.
Technical Paper

Inspection/Maintenance in the 1990's

1987-08-01
870621
In the 1990's there will be a different mix of vehicle technologies than existed in the late 1970's when inspection/Maintenance (I/M) programs were first mandated. These changes include the widespread use of “closed-loop” computer control of engine parameters and fuel injection. Several studies by EPA are examined to determine the effect of these changes on existing I/M programs and to investigate new methods of vehicle inspection. The report discusses the effectiveness of a standard idle emission test versus other inspection methods, the role of proper preconditioning, self-diagnostic trouble code checks as a method to identify high emitting vehicles, uncertainties in predicting tampering and misfueling rates for the future, problems with decentralized programs, and the effectiveness of I/M repairs in reducing vehicle emissions as measured on the Federal Test Procedure.
Technical Paper

Trends in Alternate Measures of Vehicle Fuel Economy

1986-10-01
861426
This paper develops and discusses the 1978-85 time trends in alternative measures of vehicle fuel economy. Nine alternative measures are presented ranging from ton-miles per gallon to menu-weighted performance adjusted miles per gallon. For each alternative measure, trends for important groups of manufacturers are presented. Ail of the trends in alternative measures are compared to the percent improvement implied by the original 1978 and 1985 passenger car average fuel economy standards (AFES).
Technical Paper

Light Duty Automotive Trends Through 1986

1986-04-01
860366
This, the fourteenth in this series of papers, examines trends in fuel economy, technology usage and estimated 0 to 60 MPH acceleration time for model year 1986 passenger cars. Comparisons with previous year's data are made for the fleet as a whole and using three measures of vehicle/engine size: number of cylinders, EPA car class, and inertia weight class. Emphasis on vehicle performance and fuel metering has been expanded and analysis of individual manufacturers has been deemphasized; comparisons of the Domestic, European, and Japanese market sectors are given increased emphasis.
Technical Paper

Toxicologically Acceptable Levels of Methanol and Formaldehyde Emissions from Methanol-Fueled Vehicles

1984-10-01
841357
The increased interest in use of methanol makes it important to determine what levels of methanol and formaldehyde emissions may be acceptable. This paper reviews the available health data for methanol and formaldehyde to define what approximate ranges of concentrations, termed ranges of concern, could be acceptable from a toxicological viewpoint. Air quality models are then used to predict the in-use fleet average exhaust emission levels in localized situations (heavily impacted by mobile sources) corresponding to these ranges of concern. Using predicted fleet compositions, approximate target emission levels are given for the light-duty portion of the fleet which could yield these fleet averages. Finally, there is a brief summary of available methanol and formaldehyde emissions data from neat methanol-fueled vehicles which are compared to the target levels.
Technical Paper

Development of Adjustment Factors for the EPA City and Highway MPG Values

1984-02-01
840496
This paper describes the development of adjustment factors applicable to the EPA City and Highway MPG values. The paper discusses the data bases used, and the analytical methods employed to arrive at adjustment factors of 0.90 for the EPA City MPG value and 0.78 for the EPA Highway MPG value.
Technical Paper

A Study of the Potential Impact of Some Unregulated Motor Vehicle Emissions

1983-06-06
830987
Studies of emissions from vehicles equipped with catalysts have shown that some unregulated emissions can increase when a catalyst is used. One example of this is sulfuric acid, which has been studied extensively. Other unregulated emissions include ammonia and hydrogen cyanide. In a number of studies, these unregulated pollutant emissions have been measured from light-duty vehicles and heavy-duty engines. These emission levels were used in air quality dispersion models to predict the resultant air quality levels. The ambient concentrations predicted for each pollutant were then compared to suggested concentrations at which adverse health effects may be found to determine if additional monitoring or control would be indicated for these pollutants. It was determined that mobile source emissions of sulfuric acid, hydrogen cyanide, and ammonia do not in general result in ambient levels of concern for the air quality situations studied.
Technical Paper

Light Duty Automotive Fuel Economy… Trends thru 1983

1983-02-01
830544
This, the eleventh in a series of Papers on EPA fuel economy trends, emphasizes the current Model Year (1983) as usual, but also gives increased emphasis to trends in vehicle technology, including catalyst and transmission subclasses. Final “CAFE”* production volumes and MPG figures have been used to update the data bases through the 1980 Model Year, and an analytic method used in the past to allocate year-to-year fleet MPG changes to specific causes, such as weight mix shifts, has been reinstituted. Conclusions are presented on the relation between fuel economy and emission standards, catalyst types, and transmission types.
Technical Paper

In-Use Emissions of 1980 and 1981 Passenger Cars: Results of EPA Testing

1982-02-01
820975
This paper presents the results of several emission testing programs conducted by the U.S. Environmental Protection Agency. The test vehicles were primarily 1980 and 1981 passenger cars which were obtained at random from private owners. Some 1982 models were also tested. The 1328 vehicles were selected from the Los Angeles area as well as from a number of other low-altitude locations. The test sequence included the Federal Test Procedure, the Highway Fuel Economy Test and several short cycle tests. The primary purpose of the program was to gather information on current vehicles which could be used in calculations and projections of air quality and aid development of programs to improve it. The results of the program indicate that these vehicles are capable of maintaining low emission levels although high levels are also possible due to defects, deterioration, or tampering. Inspection/Maintenance programs are a feasible and effective means for correcting high levels when they occur.
Technical Paper

Light Duty Automotive Fuel Economy … Trends through 1982

1982-02-01
820300
EPA Fuel economy figures are presented for model year 1982 cars and light duty trucks. Comparisons with the MPG figures of prior years are included. Sales penetrations of various vehicle, engine, and emission control design features are given, and domestic cars' MPG characteristics are compared to that of imports', gasoline vehicle MPG is compared to Diesel MPG, and 49-states MPG is compared to California MPG. Usage of newer vehicle technologies is continuing to increase, leading to continued growth in fuel economy capability in spite of stringent emission standards.
Technical Paper

Fuel Economy of In-Use Passenger Cars: Laboratory and Road

1981-06-01
810780
This report describes an evaluation of fuel economy of in-use passenger cars conducted by the U.S. Environmental Protection Agency during 1980. A total of 440 vehicles from the 1975-1980 model years were obtained from private owners in several cities. Each vehicle was tested according to the Federal Test Procedure and the Highway Fuel Economy Test. After the laboratory testing, the owners were asked to record their next four fuel purchases on a reply postcard. The results from the survey were analyzed and compared with the test results, estimates by the owner, and the values published in EPA's Gas Mileage Guide.
Technical Paper

Light Duty Automotive Fuel Economy …Trends through 1981

1981-02-01
810386
EPA new-model fuel economy figures are presented for passenger vehicles and light duty trucks (those with GVW ratings up to 8500 lbs). The 1981 models are emphasized, with some comparisons to prior years included. Reader familiarity with the EPA tests, data bases, and analytical methods is assumed. Principal two-way analyses include comparisons of domestic vs. import, gasoline vs. Diesel, and Federal (49-state) vs. California vehicles. Sales fractions for a number of vehicle and engine emission control design features are included. The principal finding is that increased use of newer vehicle and emission control technologies in 1981 has accompanied significant fuel economy gains in spite of the tougher 1981 emission standards.
Technical Paper

Exhaust Emissions from In-Use Passenger Cars Equipped with Three-Way Catalysts

1980-06-01
800823
This paper presents the results of an exhaust emission testing program conducted by the U.S. Environmental Protection Agency. The test vehicles were 1978–1980 passenger cars of various makes and models. Each of the 686 vehicles tested was equipped with a three-way catalyst system and was certified to California standards. The purpose of the program was to gather information on current systems in customer use for projections on the ability of the three-way system to meet emission standards of the future. The results indicate that these systems are capable of achieving low emission levels although high levels are also possible due to defects, deterioration, or tampering.
Technical Paper

Evaluation of Emission Control Technology Approaches for Heavy-Duty Gasoline Engines

1978-02-01
780646
This paper summarizes a laboratory effort toward reducing nine-mode cycle composite emissions and fuel consumption in a heavy-duty gasoline engine, while retaining current durability performance. Evaluations involved standard carburetors, a Dresserator inductor, a Bendix electronic fuel injection system, exhaust manifold thermal reactors, and exhaust gas recirculation, along with other components and engine operating parameters. A system consisting of electronic fuel injection, thermal reactors with air injection and exhaust gas recirculation, was assembled which met specified project goals. An oxidation catalyst was included as an add-on during the service accumulation demonstration. In addition, the driveability of this engine configuration was demonstrated.
Technical Paper

Emissions from Catalyst Cars Beyond 50 000 Miles and the Implications for the Federal Motor Vehicle Control Program

1978-02-01
780027
High mileage vehicles (in excess of 50,000 miles) contribute more than half of all vehicular emissions. With the new catalytic converter equipped cars, the proportional contribution of these vehicles may be even higher than for pre-catalyst vehicles. Thus a substantial portion of motor vehicle related air pollution may be caused by vehicles not subject to the manufacturer directed provisions of the Clean Air Act. This paper presents a modeling effort based on hypotheses and some preliminary data, and suggests some alternatives to combat this potential problem.
Technical Paper

Automotive Hydrocarbon Emission Patterns in the Measurement of Nonmethane Hydrocarbon Emission Rates

1977-02-01
770144
The advent of emission control technology has resulted in significant changes in both the total mass and detailed patterns of hydrocarbons emitted from automobiles. Emission rates of 56 hydrocarbons from 22 motor vehicles, including catalyst and noncatalyst configurations, were determined for the Federal Urban Driving Cycle. An increased relative abundance of methane is indicated for vehicles equipped with oxidation catalysts. In view of the photochemically non-reactive nature of methane, simple and economic procedures for determination of vehicle nonmethane hydrocarbon emission rates are evaluated. In general the procedures evaluated require independent total hydrocarbon and methane analysis, with the nonmethane hydrocarbon level calculated by difference. The procedures are evaluated by comparison of indicated nonmethane hydrocarbon emission rates with rates obtained by summation of individual compound rates determined by advanced gas chromatographic procedures.
Technical Paper

A Quality Control Technique for Correlating Exhaust Gas Analysis Systems

1977-02-01
770138
A simple, inexpensive, critical flow blender has been developed for filling a tedlar bag with controllable concentrations of HC, NOx, CO2, and CO gases at levels encountered in automobile emissions testing. According to a daily schedule, a technician takes the bag to all analyzer sites in the laboratory for analysis. The concentrations indicated by each site are compared to the overall averages. The results are stored in a computerized data base from which control charts, statistical analyses, and interpretations of significant differences among test sites can be made. The precision, accuracy, and statistical interpretations of the data are discussed.
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